A highly efficient and simple protocol for the construction of 2‐haloaromatic isothiocyanates from their respective amines in the presence of cheap, readily available and air stable iron catalyst is described. All the reactions were carried out under moderate reaction conditions could give their target products in good to excellent yields in shorter reaction time
ReferencesScans of 1 H and 13 C Spectra S11 S12-S63were purchased from Aldrich and used without further purification. The solvents were purchased and dried according to standard procedure prior to use. 1 1 H NMR (400 MHz) spectra were recorded with a Varian 400 spectrometer. Infrared (IR) spectra recorded on a Perkin Elmer Spectrum one FT-IR spectrometer. VKSI Medico Centrifuge machine was used for our experimental procedure for the synthesis of substituted cyanamides.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.