The character of interaction in the four‐c omponent ZnP2‐CdP2‐CdAs2‐ZnAs2 system and in the boundary ternary systems is investigated. Phase equilibria in the ZnP2‐CdP2‐CdAs2‐ZnAs2 system at 298 K are determined and the existence boundaries of ternary and quaternary solid solutions established.
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