Das durch Addition von Methyldichlorsilan (I) an Isopropenyl‐o‐carboran (II) in Gegenwart von Hexachloroplatinsäure oder von Eisen(III)‐chlorid dargestellte Methyl‐(o‐carboranyl‐isopropyl)‐dichlorsilan (III) liefert bei der Hydrolyse mit einem Überschuß an Wasser in Gegenwart von Natriumhydrogencarbonat als Chlorwasserstoffacceptor das Silandiol (IV).
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