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The suitability of bromine as an anionic dopant influencing the properties of CdS thin films is discussed in this paper. The as-deposited films were characterised respectively by XRD, SEM, UV-vis-NIR spectrophotometer and two-point probe setup. All the films appear to be polycrystalline in nature exhibiting hexagonal crystal structure with a (002) preferential growth texture. The 2θ value of the (002) plane shifts towards lower Bragg angle with doping inferring an expansion in their lattice volumes. Increased transparency and blue shift in optical band gap value are observed for the doped films. Electrical resistivity decreased with increase in Brdoping concentration. Increased transparency, widened band gap and decreased electrical resistivity values achieved confirm that Br is a suitable anionic dopant that can strongly influence the physical properties of pure CdS towards future optoelectronic devices.

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