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The catalytic reduction of solketal ((2,2‐dimethyl‐1,3‐dioxolan‐4‐yl)methanol) over bifunctional heterogeneous palladium catalysts is proposed as an alternative to the synthesis of glycerol isopropyl ethers by the etherification of glycerol. The direct synthesis of glycerol isopropyl ethers from isopropanol and glycerol requires severe conditions (T=130–150 °C, p(H2)=20–35 bar) and a large excess of isopropanol to reach a considerable yield. The main reaction products in the catalytic reduction of solketal are glycerol mono‐ and di‐isopropyl ethers and solketal isopropyl ether. Solketal conversion over Al‐HMS‐supported palladium catalysts (T=120 °C and p(H2)=20 bar) affords a mixture of ethers with a high degree of conversion (87 %), 78 % selectivity, and excellent regioselectivity between isomeric ethers. Zeolite‐BEA‐supported palladium catalysts also exhibit high activity but much lower selectivity because of intense acetone aldol condensation. The effects of Si/Al ratios in BEA zeolites and Al‐HMS aluminosilicates and the amounts of supported palladium (1 and 2 wt %) on the properties of the catalysts at different reaction temperatures and hydrogen pressures are considered.