The catalytic activity in the soot combustion is reported for a series of potassium-promoter alumina supported catalysts prepared by the sol-gel method to be used in the catalytic combustion of soot. The studied systems correspond to CeO 2-Al 2 O 3 and La 2 O 3-Al 2 O 3 with charges of 3 and 5 wt% of CeO 2 and La 2 O 3. Potassium impregnation is performed to reach 3 atoms of K per nm 2 of the mixed oxide. The effect of the potassium incorporation increases its reducibility, decreases the surface area and forms a new type of oxygen that is stronger than the oxygen in mixed oxides with similar chemical nature. The existence of potassium oxides, K 2 O and oxygen responsible for the vacancies and/or lattice defects (O 2−) are related to good catalytic activity. Additionally, the presence of alkali affects the structural and textural characteristics of the catalyst, promoting the catalytic activity in soot combustion.
CUBA
RESUMENSe presentan resultados obtenidos en el estudio cinético realizado al sistema de molienda de la fábrica de cemento de "Palmarito de Cauto ", Santiago de Cuba, con vistas a la producción de cementopuzolánico PZ'250 con adición de hasta un 40 % de puzolanas.
El presente trabajo avala satisfactoriamente las predicciones realizadas y permiten recomendar su utilización como un medio idóneo de eficiencia económica.
SUMMARY
A kinetic study realized in a moulding system in a cement factory ("Palmito de Cauto " Santiago de Cuba) is presented. This objective of this study is the production ofapozzolonic cement PZ-250 with an addition until 40% ofpozzolan.The present paper confirms the satisfactory predictions and permits to recommend the utilization it as a available way of economical efficiency.
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