The present work involved the production of Metal Matrix Composites (MMCs) of Aluminium Silicon (Al-Si) alloy reinforced with Multi Walled Carbon Nano Tubes (MWCNTs) using Powder Metallurgy (PM) process. MWCNTs with concentrations of 0, 0.25, 0.5, 0.75 and 1.0 wt% were used. Validation of dispersion nature, existence and chemically stable of MWCNTs carried out using Transmission Electron Microscope (TEM), X-ray Diffractometer (XRD) and Energy Dispersive Spectrum (EDS) for fabricated composites. Sliding wear investigations were investigated in accordance with the ASTM G99-95a standard. Test variables such as sliding distance, load and speed were examined. Under a given load with sliding distance, the wear rate was found to reduce by varying disc rotation speed between 250 to 750 rpm. The rate of wear is dropped suddenly with the increment in sliding distance from 500 m to 1000 m. However, for 1500 m sliding distance, the wear rate increased linearly for all nanocomposites. The reinforcement of 0.25 wt% and 0.5 wt% of MWCNTs shown lower wear resistance and further addition of 0.75 wt% MWCNTs shown enhanced wear resistance but the addition of reinforcement of above 0.75 wt% resulted in slightly higher wear rate. The wear resistance enhanced due to the excellent properties of reinforcement particles. The Scanning Electron Microscope (SEM) was used for identifying the kind of wear mechanism.