Atmospheric contaminants from marine-industrial environments could cause corrosion damage on steel A36 usually used in equipment and machinery. Therefore, it is desirable to study the corrosion phenomena in different micro-environments and formulate adequate protection measures. In this study, three micro-environments were selected and categorized according to ISO-12944-2 standard as C5-I and C5-M. Four multilayer-coating schemes were used on each exposure site to evaluate their performance. Corrosion products were analyzed using XRD, raman and UV-Vis techniques. The results showed that the best system was composed of a flake-filled-epoxy/polyamides/epoxy-siloxane. The results confirmed the influence of atmospheric contaminants on overall behavior from different location.