To clarify the individual effect of secondary forces on the self‐assembly of molecules, a chiral cholesteryl N‐(2‐anthryl) carbamate (CAC) consisting of anthryl, carbamate, and cholesteryl groups was synthesized. From the results of the temperature‐dependent 1H NMR, the hydrogen bond‐assisted π–π interaction was found to maintain the growth of the axis of the self‐assembled structure, and the three‐dimensional effect from the cholesteryl group induces the rotational structure. Fluorescence behavior of the CAC molecules with and without assistance of secondary forces was investigated. Thermoswitchable fluorescence of gelators was observed. Supramolecular organogels reveal significant enhanced fluorescence strength due to the aggregation‐induced enhanced emission of the CAC molecules. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013
Sintered SiC ceramics with difficulty, and its production process and production are more expensive, lower sintering temperature of SiC ceramics and look for new low-cost production process is the focus of materials research workers. Re-crystallization of SiC components of the raw materials requirements of high purity, can not add sintering aids, sintering temperature up to about 2450°C). In this paper, by improving and optimizing the existing production process, to lower the sintering temperature of the new methods and ideas, the study shows that: β-SiC will be added to the sintered α-SiC slurry, and the best particle size ratio of α: β = 15:1 mixture, at the same time, according to re-crystallization of SiC sintering theory, the fine particles (β-SiC, has played the role of sintering agent) adsorption in the coarse particle (α-SiC, the role of the support skeleton) and can greatly reduce the SiC Sintering temperature (50-100°C), and to improve the purity of α-SiC, the most economical way to prepare a high-density, high oxidation resistance, high impact resistance, high strength, high mechanical properties of recrystallized SiC powder .
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
customersupport@researchsolutions.com
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.