Novel
complex C2-quaternary-indol-3-one units bearing versatile
nitro groups have been successfully developed from pseudo-indolones
and α,β-unsaturated nitroolefins through rhodium-catalyzed
C–H activation/[3 + 2] spirocyclization. Notably, four diastereomers
could be selectively obtained in the reaction by condition control.
Rhodium(III)‐catalyzed cross‐dehydrogenative coupling involves a highly efficient C−C bond formation from N‐phenyl‐7‐azaindole frameworks, thiophenes. Various novel 7‐azaindole derivatives have been successfully developed with good substrate applicability.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.