A novel carbon fiber‐reinforced ZrB2–SiC matrix composite was fabricated by heaterless chemical vapor infiltration through infiltration of SiC matrix into a carbon fiber‐ZrB2 powder preform. The C/ZrB2–SiC composite presented a flexural strength of 148 MPa, a fracture toughness of 5.6 MPa·m1/2, and a good oxidation and ablation resistance.
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