As a typical class of single‐atom catalysts (SACs) possessing prominent advantages of high reactivity, high selectivity, high stability, and maximized atomic utilization, emerging metal‐nitrogen‐doped carbon (M‐N‐C) materials, wherein dispersive metal atoms are coordinated to nitrogen atoms doped in carbon nanomaterials, have presented a high promise to replace the conventional metal or metal oxides‐based catalysts. In this work, recent progress in M‐N‐C‐based materials achieved in both theoretical and experimental investigations is summarized and general principles for novel catalysts design from electronic structure modulating are provided. Firstly, the applications and mechanisms on the advantages and challenges of M‐N‐C‐based materials for a variety of sustainable fuel generation and bioinspired reactions, including the oxygen reduction reaction (ORR), oxygen evolution reaction (OER), hydrogen evolution reaction (HER), carbon dioxide reduction reaction (CO2RR), nitrogen reduction reaction (NRR), and nanozyme reactions are reviewed. Then, strategies toward enhancing the catalytic performance by engineering the nature of metal ion centers, coordinative environment of active centers, carbon support, and their synergistic cooperation, are proposed. Finally, prospects for the rational design of next generation high‐performance M‐N‐C‐based catalysts are outlined. It is expected that this work will provide insights into high‐performance catalysts innovation for sustainable and environmental technologies.

The East Asian summer monsoon affects precipitation and hence vegetation in the densely populated Northwest Pacific region, yet a long-standing controversy exists concerning the spatial and temporal dynamics of the Holocene Optimum (HO) in the East Asian Monsoon Region. Here we use a detailed 14,000-year record reconstructing vegetation variations from a strategically selected crater lake from Northeast China, as well as a compilation of previous paleoclimatic studies, to show that the HO began around 6,000 Cal a BP in Northeast China, significantly later than generally recognized. By comparing our paleoenvironmental data with Holocene vegetation records from other regions of East Asia, we identified a marked northward shift for the onset of the HO from ~10,260 Cal a BP in South China to ~6,000 Cal a BP in Northeast China. The gradual northward transgression of the vegetation change could be caused by both the temperature and precipitation changes in different regions. Finally, we fitted a regression model of the start of the HO period versus latitude, which allowed us to make predictions for the beginning of the HO based at different geographical locations. This study reveals a strong relationship between latitude and the initiation of the HO, and provides a window towards better understanding the forcing of vegetation changes in the East Asian monsoon region.

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It is assumed that the potential intensity of tropical cyclones (TC) will increase with rising global temperature. The western North Pacific is one of the three principal TC centers, but TC records from the region are scarce and sometimes controversial. Here we present grain‐size distributions and element contents of sediment cores from the East China Sea, in the western North Pacific. We interpret changes in the mean grain size of the coarse fraction as a proxy for TC intensity, and we infer a linkage of TC intensity to temperature changes over the last two millennia. Supported by model simulations, our results show that TC intensity increased (decreased) during relatively warm (cool) periods, confirming the control of temperature on TC intensity on a multicentennial scale. Our results suggest that long‐term TC intensity in the western North Pacific may increase with continued global warming.

The risk of large, devastating tsunamis in the South China Sea and its surrounding coastal region is commonly underestimated or unrecognized due to the difficulty of differentiating tsunami from storm deposits. As a consequence, few convincing records have documented tsunami deposits in this region. Here we report preliminary evidence from Xisha Islands in the South China Sea for a large tsunami around AD 1024. Sand layers in lake sediment cores and their geochemical characteristics indicate a sudden deposition event around AD 1024, temporally consistent with a written record of a disastrous event characterized by high waves in AD 1076. Heavy coral and shell fossils, which are older than AD 1024, deposited more than 200 meters into the island, further support the occurrence of a high-energy event such as a tsunami or an unusually large storm. Our results underscore the importance of acknowledging and understanding the tsunami hazard in this area.