No abstract

Shape memory polymers (SMPs) can be used to produce a new class of decorative films capable of improved formability and shape recovery in polymer laminates, which are increasingly being used for automotive, aerospace, construction and commercial applications. As a relatively new field there is little knowledge on the shape recovery behaviour of laminates with a SMP film and few methods of quantify that behaviour. The influences of different variables that affect the recovery behaviour of thermoplastic shape memory polyurethanes based laminates including ambient temperature (45 °C and 65 °C), material modulus, and adhesive strength were investigated after thermoforming, through both experimental and modelling methods. The empirical model assisted in identifying the contributions of the adhesive to transfer stresses, which dampened the recovery of the laminate with lower shear strength adhesives. Increasing ambient temperature and the film modulus increased both the final angle recovery ratios and recovery rates.