A method for enantioselective direct α-amination reaction catalyzed by a sterically "frustrated" Lewis acid/Brønsted base complex is disclosed. Cooperative functioning of the Lewis acid and Brønsted base components gives rise to in situ enolate generation from monocarbonyl compounds. Subsequent reaction with hydrogen-bond activated dialkyl azodicarboxylates delivers α-aminocarbonyl compounds in high enantiomeric purity.

A density functional theory and wave function theory investigation on the geometrical and electronic structures of B5O4(0/-) clusters has been performed in this work. B5O4(-) anion proves to possess a perfect tetrahedral ground state of T(d) B(BO)4(-) ((1)A1) analogous to BH4(-) with four equivalent -BO terminals around the B center, while B5O4 neutral favors a slightly off-planed C(s) B(BO)4 ((2)A') which contains three -BO terminals and one -O- bridge. An intramolecular BO radical transfer occurs from T(d) B(BO)4(-) to C(s) B(BO)4 when one electron is detached from the anion. The one-electron detachment energies of the anion and characteristic stretching vibrational frequencies of -B=O groups at about 2000 cm(-1) have been calculated to facilitate future experimental characterization of these clusters.

An ab initio theoretical investigation has been performed on planar or quasi-planar octa-and ennea-coordinate Al and Ga centered in X@B 8 − and X@B 9 (X=Al, Ga). These high symmetry molecular wheels all turned out to be true minima of the systems and σ+π double aromatic in nature, similar to the previously characterized D 8h B@B 8 − both electronically and geometrically. Adiabatic and vertical detachment energies of the anions and the ionization potentials of the neutrals have been calculated to aid their eventual experimental identification.planar hyper-coordinate, aluminum, gallium, ab initio, geometry, electronic structure

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