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AbstractThe preparation of sulfur dioxide complexes M(SO2)2(AsFe) (1 a-1 g M = Mn, Fe, Co, Ni, Cu, Zn, Mg) is possible in liquid SO2 (a) by oxidation of the metals with AsF5, (b) by metathesis of metal halides, e.g. NiBro, with AgAsF6, (c) by the reaction of metal fluorides, e.g. ZNF2, with AsF5. The spectroscopic properties of these complexes are discussed and the structure of [Mg(SO2)2(AsF6)2]n (1 g) is reported.

Die Umsetzungen von Sulfonylschwefeldiimiden rnit Alkalialkoholaten fuhren zu den Salzen l a -g. Eine Rontgenstrukturanalyse von I f zeigt die erwartete Geometrie rnit dem zentralen dreifach koordinierten Schwefelatom. l c reagiert rnit elementarem Chlor zum Natriumsalz 2 der azaanalogen Chlorsulfonsaure. Setzt man NaNH, als Nucleophil rnit Bis(phenylsulfony1)schwefeldiimid um, so entsteht als Hauptprodukt Tris(phenylsulfony1imido)sulfit (3), dessen Struktur ebenfalls durch eine Rontgenstrukturanalyse aufgeklart wurde. Analog dem SO:--Anion besitzt in 3 das zentrale Schwefelatom trigonal pyramidale Konfiguration. Die azaanaloge Verbindung 4 der Fluorsulfinsaure entsteht bei der Reaktion von Bis(phenylsulfony1)schwefeldiimid mit sorgfaltig getrocknetem CsF. Bei der Umsetzung von Bis(trimethylsi1yl)schwefeldiimid rnit CsF, das etwa 7% Wasser enthalt, bildet sich das monomere Caesiumsalz des Sulfimids, das nach Kationenaustausch in Form der Salze 5a und b charakterisiert wurde. Tetraphenylphosphoniummethoxid reagiert rnit 5-(Trimethylsilyloxy)-l ,3h4,2,4,6-dithiatriazin-1 ,1-dioxid (6) unter CH,OSi(CH,),-Abspaltung zu 7. Das Anion von 7 enthalt eine Carbonylgruppe. Anions of Sulfur with the Coordination Number 3: Synthesis, Structure, and Range of ExistenceSulfonylsulfur diimides react with alkali alcoxides to form the salts l a -g . An X-ray structural analysis of I f shows the expected geometry with the central threefold coordinated sulfur atom. l c reacts with elemental chlorine to yield the sodium salt 2, the aza analogue of chlorosulfonic acid. When NaNH, is used as a nucleophile for the reaction with bis(phenylsulfony1)sulfur diimide, tris(phenylsulfony1imido)sulfite (3) is formed as the main product. Also the structure of 3 was elucidated by means of an X-ray analysis. Analogous to the SO:--anion, 3 has a central sulfur atom with trigonal pyramidal configuration. The analogous aza compound of the fluorosulfinic acid 4 is formed by the reaction of bis(phenylsulfony1)sulfur diimide with carefully dried CsF. By the reaction of bis(trimethylsily1)sulfur diimide with CsF, which contains about 7% of water, the monomeric cesium salt of sulfonimide is formed. The salts 5a und b were obtained by cation exchange of the cesium salt. Tetraphenylphosphonium methoxide reacts with 5-(trimethylsilyloxy)-1 ,3h4,2,4,6-dithiatriazin 1 ,I-dioxide (6) by elimination of CH,OSi(CH,), to yield 7. The anion of 7 contains one carbonyl group.Kationen des Schwefels rnit der Koordinationszahl 3 werden in zahlreichen Publikationen' -, ) beschrieben. Entsprechende Anionen des Schwefels sind praktisch nur vom 0 Verlag

Translation of the Bible or any other text unavoidably involves a determination about its meaning. There have been different views of meaning from ancient times up to the present, and a particularly Enlightenment and Modernist view is that the meaning of a text amounts to whatever the original author of the text intended it to be. This article analyzes the authorial-intent view of meaning in comparison with other models of literary and legal interpretation. Texts are anchors to interpretation but are subject to individualized interpretations. It is texts that are translated, not intentions. The challenge to the translator is to negotiate the meaning of a text and try to choose the most salient and appropriate interpretation as a basis for bringing the text to a new audience through translation.

The complete manuscript of this communication appears in: Angew. Chem. Suppl. 1982, 269. DOI:10.1002/anie.198202690