We investigated the thermal stability of exo-tetrahydrodicyclopentadiene (exo-THDCP, C 10 H 16 ) in the absence and presence of 1,2,3,4-tetrahydroquinoline (THQ), which acts as a hydrogen donor (H-donor). It was found that conversion of exo-THDCP was faster at the higher temperature. The increase in the rate of
In this study, highly luminescent carbon dots with diameters of 3–5 nm were synthesized via the carbonization of citric acid, and the effects of surface passivation and carbonization temperature on the optical properties were investigated.
Highly luminescent Cd-free Zn doped CuInS(2) nanocrystals (ZCIS NCs) were synthesized, and their properties were evaluated using X-ray diffraction, Raman, UV, and photoluminescence. The crystal structure of the ZCIS NCs was similar to the zinc blende, and the lattice constant decreased with increasing Zn concentration. By incorporation of Zn, the emission wavelength was tuned from 536 to 637 nm with concomitant enhancement of the quantum yield up to 45%. A white light emitting diodes, integrating dual ZCIS NCs (λ(em) = 567, and 617 nm) and a 460 nm InGaN LED, exhibited a high color rendering index of 84.1 with a warm color temperature of 4256.2K. The CIE-1931 chromaticity coordinates were slightly shifted from (0.3626, 0.3378) at 20 mA to (0.3480, 0.3206) at 50 mA.
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