To assess downward positions of water spray for the small-scale release of chlorine gas, dispersion coefficients for the Gaussian dispersion model were validated at the small-scale release experiment. And the downwind distances of water spray were assessed with the simulated results. As results, the Gaussian plume model using the Briggs' dispersion coefficient well estimated the dispersed characteristics for small-scale release of chlorine gas. The best adequate downwind position of water spray is the position of the maximum concentration of chlorine at the ground level. And the adequate vertical and horizontal dimensions of water spray consider the maximum width and height of cloud.