The Sn atom in the title compound, [SnBr(C6H5)2(C3H6NS2)], adopts a distorted SnBrC2S2 trigonal–bipyramidal environment.

The Sn atom of the title compound, [Sn(C10H13)3(C10H6NO4)], is four‐coordinate and possesses a distorted tetra­hedral geometry.

Key indicatorsSingle-crystal X-ray study T = 295 K Mean (C-C) = 0.009 Å Disorder in main residue R factor = 0.037 wR factor = 0.110 Data-to-parameter ratio = 17.8For details of how these key indicators were automatically derived from the article, see

In the centrosymmetric title compound, [Sn2(C10H13)6(C4H2O4)], the Sn atom adopts a distorted tetrahedral SnC3O geometry, with a mean Sn—C distance of 2.143 (3) Å and with Sn—O = 2.070 (2) Å. A short Sn...O contact of 3.072 (4) Å is also present.

The Sn atoms of the monomeric title compound, [Sn2(C6H11)6S], display slightly distorted SnSC3 tetrahedral geometries, with mean Sn—C and Sn—S distances of 2.163 (6) and 2.4089 (14) Å, respectively. The bridging Sn—S—Sn angle is 113.43 (5)°.