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Spin polarization of an Fe/MgO(100) surface oxidized at room temperature has been analyzed with a spin-polarized metastable helium beam, which is an extremely surface sensitive spin probe, under high magnetic fields (0–50 kOe). The spin polarization of the Fe surface, although it initially decays with oxygen exposure, increases at >20 L (1 L=10−6 Torr sec) and becomes comparable to that observed for a clean Fe surface at >100 L. The polarization is negative and especially high at around the Fermi level. This may be understood if we assume the formation of Fe3O4.

A convenient, divergent strategy for the synthesis of a series of modular and fine-tunable C3-TunePhos-type chiral diphosphine ligands and their applications in highly efficient Ru-catalyzed asymmetric hydrogenations were explored. Up to 97 and 99% ee values were achieved for the enantioselective synthesis of beta-methyl chiral amines and alpha-hydroxy acid derivatives, respectively.

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