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We proposed a novel bromine quaternary ammonium ligand to synthesize high quantum yield (QY) CsPbBr3 quantum dots (QDs). The QY of CsPbBr3 QDs synthesized by this ligand reached 95% and the full width at half maximum (FWHM) was as narrow as 17nm. The peak wavelength of the prepared CsPbBr3 QDs was 530nm. And these QDs emitted high purity green light under ultraviolet light. The color coordinate of white LED (WLED) prepared with the CsPbBr3 QDs was (0.29, 0.31), which was very close to pure white light. The color gamut of the WLED covered 130% of the national television system committee (NTSC) color standard and 96% of the ITU-R Recommendation BT.2020 (Rec.2020) color standard.