Under the globalized and fiercely competitive external environment, manufacturers have to enhance the organizational learning capability to cope with the challenge of Environmental Education. In addition to developing and cultivating the knowledge management capability, manufacturers have to co-develop, share, and spread relevant knowledge among different bodies in the external network. The theoretical relationship among manufacturers' knowledge management in global manufacturing network, knowledge management in supply chain network, and organizational learning capability is proposed in this study, and the moderation effect of Environmental Education is further discussed. Based on 2013 International Manufacturing Strategy Survey VI (IMSS VI) of 463 manufacturers in 22 countries and regions. The empirical research results are concluded as below. (1) Manufacturers' knowledge management in global manufacturing network and knowledge management in supply chain network present remarkably positive effects on the organizational learning capability. (2) Manufacturers' knowledge management in supply chain network shows mediation effects on the relationship between knowledge management in global manufacturing network and organizational learning capability. (3) Environmental Education reveals notable moderation effects on the relationship between manufacturers' knowledge management in supply chain network and organizational learning capability.

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