Two ion-pair Fe(III) complexes of (PPh4)[FeIII(HATD)2]·2H2O (1,H3ATD = azotetrazolyl-2,7-dihydroxynaphthalene) and [FeII(phen)3][FeIII(HATD)2]2·3DMA·3.5H2O (2, phen = 1,10-phenanthroline, DMA = N,N-dimethylformamide) were synthesized employing the tridentate ligand of H3ATD. The crystal structural analysis...
An azo-based ligand of azotetrazolyl-2,7-dihydroxynaphthalene (H3ATD) was used to synthesize three FeIII–MII–FeIII (M = Fe, Cd) linear trinuclear complexes with different high temperature spin crossover (SCO) behaviours for the terminal FeIII ions.
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