High efficient and non-precious metal electrocatalysts for oxygen evolution reactions (OER) and oxygen reduction reactions (ORR) are at the heart of key renewable-energy technologies. Nevertheless, developing highly-active bi-functional catalysts at low cost for both OER and ORR still remains a huge challenge. In this paper, Co3O4 nanocrystals embedded in N-doped mesoporous graphitic carbon layer/multiwalled carbon nanotubes (MWCNTs) hybrids are prepared by a facile carbonization and subsequent oxidation process of MWCNTs-based metal-organic framework (MOF). As a result, in alkaline media, the hybrid material catalyzes OER with an onset potential of 1.50 V (vs reversible hydrogen electrode) and over-potential only of 320 mV to achieve a stable current density of 10 mA cm -2 for at least 25 h. The same hybrids also exhibit similar catalytic activity but superior stability to commercial 20 wt% Pt/C catalyst for ORR, making it a high-performance cheap bi-catalyst for both OER and ORR. The design concept of nonmetal-doped and precious-metal-free electrocatalysts from MOF can be extended to fabricate other novel, stable and easy to use catalyst system for advanced applications.
The results indicated that obesity was associated with the risk of gastric cancer, especially for males and among non-Asians. Both overweight and obesity were associated with the risk of gastric cardia cancer.
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