Herein, we have employed LR-TDDFT-based nonadiabatic dynamics simulations to investigate the ultrafast charge transfer in a nonfullerene all-small-molecule donor-acceptor (D-A) system formed by a porphyrin small-molecule donor ZnP and a...

An “umpolung relay” strategy, which includes an one-pot, twice polarity inversion cascade of C60 via carbanion and carbocation polarity reversed relay pathway, has been developed for the synthesis of a diverse range of novel [60]­fulleroindole derivatives.

An unprecedented multicomponent domino reaction of [60]fullerene, indole, and DMSO/HCl has been developed for the one-pot efficient synthesis of diverse N-substituted [60]fulleroindole derivatives. This methodology features simple operation, low cost, and transition-metal-circumvented and good functional group tolerance in indole.

Correction for ‘One-pot, three-component regioselective coupling reaction of triphenylamine/carbazole derivatives with [60]fullerene and indoles via an “umpolung relay” strategy’ by Xin-Rui Chen et al., Org. Chem. Front., 2021, DOI: 10.1039/D1QO01058A.