An anionic three-dimensional framework {(Me2NH2)2[Zn8(L)6(ad)4(μ4-O)]·10DMF·11H2O}(Zn-MOF, L2-=4,4'-(3-aminopyridine-2,5-diyl)dibenzoic acid, ad-=adeninate) with a column-layered structure was synthesized. Structural studies show that the Zn-MOF has octahedral cages [Zn8(ad)4(μ4-O)], adjacent cages are connected by O...
The two structurally similar columnar ZnII-MOFs {[Zn8L4(TZ)4·0.5H2O]·4[Me2NH2]·6DMF·4H2O}n (Zn-MOF 1) and {[Zn4L2(MT)2·H2O]·2[Me2NH2]·4DMF·4H2O}n (Zn-MOF 2) were synthesized by irregular ligand, 2,2′-(pyridine-2,6-diyl) diterephthalic acid (H4L), 1,2,4-triazolium (TZ) and 1H-1,2,4-triazole-3-thiol (MT). Structural studies showed...
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