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1998) Synthesis and x-ray crystal structure of a 24-membered macrocyclic binuclear cadmium(ii) complex with pendant arms, Journal of Coordination Chemistry, 43:4, 281-288, A new binuclear cadmium(I1) macrocyclic complex has been synthesized by [2 + 21 Schiff base condensation of tris(2-aminoethyl jamine (tren) with sodium 2,6-diformyl-4-bromophenolate (sdbp) in the presence of Cd2+ ion. The crystal structure of the complex [Cd2L](C104)2.0.5CHgOH has been determined by X-ray methods. Crystals are monoclinic, space group P2,lc with a = 11.633(15), h = 16.370(2), c = 21.193(2) A, p = 96.121(12j0, Z = 4, V = 4013.0(8) A3, F(O00) = 2180, D, = 1.841 g cm-', p = 32.46 cm-', R = 0.049, R,, = 0.069. Two cadmium(I1) ions are bridged by two p2-phenoxy oxygen atoms. Each cadmium lies in a N402 coordination environment. Coordination geometry around Cd(I1) is a capped trigonal bipyramid. Coordination of phenoxy oxygens and terminal amino groups enhances the stability of the complex.

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