Colloidal nanocrystals (NCs) with radial-position-controlled doping were synthesized to study the effect of the binding symmetry around Mn2+ dopant. For the four samples ZnSe:Mn/ZnSe, ZnSe/ZnS(2 ML):Mn/ZnS(2 ML), ZnSe/ZnS(1 ML):Mn/ZnS(2 ML), and ZnSe:Mn/ZnS(2 ML), which were in sequence of binding asymmetry around Mn2+ dopant, their photoluminescent (PL) peak showed gradual red-shift (579 to 599 nm) and the PL lifetime became monotonously shorter (0.57 to 0.31 ms), while, as indicated in the electronic paramagnetic resonance spectra, the hyperfine splitting constant became larger (67.9 to 68.4 G) and the g factor became smaller (2.0076 to 2.005). The relation between the luminescent and magnetic properties of the Mn-doped NCs was discussed.

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