Recently, the choice of ligand and geometric control of mononuclear complexes, which can affect the relaxation pathways and blocking temperature, have received wide attention in the field of single ion-magnets...

A novel one-dimensional (1D) polymeric cyanometallate- and carbonate-bridged dysprosium(III) chain with the formula [Dy2(LN5)2{Fe(CN)6}(CO3)(OH)] (1), where LN5 is 2,14-dimethyl-3,6,10,13,19-pentaazabicyclo[13.3.1]nonadeca-1(19),2,13,15,17-pentaene, was synthesized, providing the first example of the 3d-4f chain complex...

Two seven-coordinate Co(II)-nitrate complexes, [Co(tmpdc)(NO3)2] (1) and [Co(tmpdt)(NO3)2]∙CH3CN (2) (tmpdc = N,N,N’,N’-tetramethyl-2,6-pyridinedicarboxamide, tmpdt = N,N,N’,N’-tetramethyl-2,6-pyridinedithiocarboxamide) with tridentate neutral ligands tmpdc or tmpdt have been prepared. Their crystal structures by single...