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Mesoporous MCM-41 molecular sieve was synthesized hydrothermally and selected tetraethoxysilane as silica source. Solid superacid was supported on MCM-41 by dipping and roasting. The samples were characterized by XRD, TEM, and FT-IR. Solid superacid evenly dispersed on MCM-41 with a good pore structure. Their catalytic activities were evaluated in the isomerization of α-pinene. The results show that samples had a good conversion rate and selectivity.

Mesoporous MCM-41 molecular sieve was synthesized hydrothermally and selected tetraethoxysilane as silica source. Solid superacid SO42-/ SnO2was supported on MCM-41 by dipping and roasting. The samples were characterized by XRD, TEM, and FT-IR. Solid superacid evenly dispersed on MCM-41 with a good pore structure. Their catalytic activities were evaluated in the isomerization of α-pinene. The results show that samples had a good conversion rate and selectivity.

We report the supramolecular self-assembly of cucurbit[8]uril(Q[8]) and 1-(4-methoxyphenyl)piperazine inclusion complex. The complex is cultured in 3 M hydrochloric acid solution under CdCl2 induction conditions to obtain a new crystal, the structure of which was characterized by X-ray single-crystal diffraction. The results show that the crystal belongs to the monoclinic crystal system with a C2/m space group. The host–guest interaction ratio of Q[8] and 1-(4-methoxyphenyl) piperazine is 1:2.