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O-Perfluoropyridin-4-yl group was first installed onto cycloketone oximes as a new electrophore, which was proven to be efficient iminyl radical precursors under photocatalytic and thermal conditions. A range of O-perfluoropyridin-4-yl oximes were successfully utilized in C­(sp2)–C­(sp3) bond formations of quinoxalin-2­(1H)-ones and alkenes, providing facile accesses to a range of functionalized alkylnitriles.

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In this paper, we present a computationally simple yet effective image recoloring method based on color harmonization. Our method permits the user to obtain recolored results interactively by rotating a harmonious template after completing color harmonization. Two main improvements are made in this paper. Firstly, we give a new strategy for finding the most harmonious scheme, in terms of finding the template which best matches the hue distribution of the input image. Secondly, in order to achieve spatially coherent harmonization, geodesic distances are used to move hues lying outside the harmonious sectors to inside them. Experiments show that our approach can produce higher-quality visually pleasing recolored images than existing methods. Moreover, our method is simple and easy to implement, and has good runtime performance.

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