An
effective strategy was reported to fabricate poly(ethylene vinyl
alcohol) (EVOH) nanocomposites with well-dispersed thermally reduced
graphene (TRG) sheets in a polymer matrix via a solution-mixing method.
TRG was successfully exfoliated into few-layer isolated nanosheets
by rapid heating of dry graphene oxide powders under inert gas and
high temperature. The resultant TRG/EVOH composites turned out to
have a 280% increase in tensile strength (30.5 MPa) and a 400% increase
in Young’s modulus (1111.7 MPa) by adding only 4.0 wt % TRG,
compared to those of neat EVOH. Moreover, the permeability coefficient
of O2 for the TRG/EVOH nanocomposite films with only 0.5
wt % TRG loading is significantly decreased to 8.517 × 10–15 cm3 cm cm–2 s–1 Pa–1, which is nearly 1671 times lower than that
of neat EVOH films. Therefore, the TRG/EVOH nanocomposites offer excellent
potential applications as packaging materials to extend the shelf
life of perishable goods and prescription medicines.
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