The influence of strontium impurities on silicon substrates was evaluated in order to introduce high dielectric constant SrTiO3 thin films into the LSI manufacturing process. Sr metal impurities were intentionally diffused into silicon during annealing at 950° C in N2 for 4 h. A 5-nm-thick SiO2 layer was formed when inserting wafers in and taking them out of the furnace, and the Sr impurity concentration was maximum beneath the SiO2/Si interface. Sr impurities cause an increase in positive charge in the SiO2 layer. However, the recombination lifetime of minority carriers in Si is not degraded by Sr impurities, even for Sr levels up to 1014 atoms/cm2. After annealing at 700° C in O2 for 2 h, no Sr was detected on the surface of a Si wafer facing a wafer covered with a SrTiO3 thin film prepared by metal organic chemical vapor deposition. Therefore, it is believed that Sr can safely be introduced into the LSI manufacturing process.
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