Effective recovery of dyes and salts from textile wastewater by nanofiltration (NF) remains a serious challenge due to the high consumption of water and energy caused by the limited performance of the available membranes. Herein, a novel strategy is described to prepare loose polyester NF membranes by using renewable quercetin as the aqueous monomer for fractionation of high salinity textile wastewater with minimal water and energy consumption. Compared with NF270, taken as the reference membrane, the QE-0.2/TMC-0.2 membrane significantly improved the efficiency for dye/salt fractionation by 288%. The water consumption was also decreased by 42.9%. The efficiency is attributed to an ultrahigh water permeance of 198 ± 2.1 L −1 m −2 h −1 bar −1 with a high selectivity of 123 (extremely low NaCl rejection of 1.6% and high Congo red rejection of 99.2%). The optimal quercetin-based membrane had an ultrathin separation layer of about 39 ± 1.2 nm with good hydrophilicity and negative charge density. Moreover, this work includes a novel method of comparison with a theoretically ideal membrane, which shows that both the energy and water consumption are near their theoretical minimum. This strategy is expected to save energy and minimize carbon emissions for membrane-based wastewater treatment systems.

The hybrid technology of CO 2 capture−mineral carbonation (CCMC) using alkaline streams has emerged in recent years. However, thus far, there has been no comprehensive study revealing the mechanisms of the simultaneous CCMC process regarding the choice of amine types and sensitivity of parameters. Combining with the analysis of multistep reaction mechanisms for different amines, we investigated a representative from each category in CCMC using calcium chloride to simulate the alkaline resource after leaching, i.e., primary (ethanolamine, MEA), secondary (diisopropanolamine, DIPA), tertiary (diethylethanolamine, DEAE), and triamine (diethylenetriamine, DETA), respectively. In the adsorption step, increasing the amine concentration beyond 2 mol/L reduced the absorption efficiency of DEAE due to the hydration mechanism, motivating a rational choice of concentration. In CCMC sections, when the amine concentration increased, only DEAE exhibited an increased carbonation efficiency of up to 100%, while DETA showed the lowest conversion. The carbonation of DEAE demonstrated the least sensitivity to temperature. The crystal transformation experiments suggested that over time, the produced vaterite could completely transform to calcite or aragonite, except those from DETA. Thus, with rationally chosen conditions, DEAE was demonstrated ideal for CCMC. These findings obtained in this work provided a theoretical foundation for designing future CCMC processes.

Background Left bundle branch pacing (LBBP) has been proved to maintain electrical synchrony better than RVP during mid to long-term follow-up, but little is known about the left ventricular (LV) mechanical changes over time. This study investigates if LBBP causes less sequential electro-mechanical alterations in LV that develop over time, compared with both conventional (CRVP) and leadless (LRVP) RVP. Methods Sixty-five patients with pacing indication for bradycardia were prospectively enrolled: Twenty-two were treated with LBBP, 23 with CRVP and 20 with LRVP. QRS duration (QRSd) was measured at baseline and during follow-up. All patients underwent echocardiography at baseline, one week after implantation and at one-year follow-up. LV volumes, ejection fraction (EF) and global longitudinal strain (GLS) were measured. Septal flash (SF), apical rocking and septal longitudinal strain patterns were assessed visually by two experienced readers. Results All the patients presented with normal strain pattern and no signs of SF or apical rocking at baseline. 100% of CRVP and 95% of LRVP patients had stage1 or 2 septal deformation patterns at week 1, and the majority (72.3% CRVP and 83.3% LRVP) progressed to stage≥2 at 12 months. On the contrary, over 2/3 of LBBP patients preserved normal strain patterns at week 1, and less than 1/3 had stage-1 pattern, 2 out of whom progressed to stage-2 during follow-up (Figure 1). At week 1 and 12 months, all RVP patients had SF, and most of them also exhibited apical rocking (87%-94.4% in CRVP and 80%-94.4% in LRVP). However, much less septal flash and apical rocking was induced in LBBP patients at week 1 and last follow-up (27.3%-37.5% and 22.7%-25%, P<0.001 vs RVP). Baseline QRSd were similar among three groups. At week 1, the paced QRSd increased least in LBBP compared to CRVP and LRVP and remained as such at 12 months. During one year follow-up, LVEF and LV GLS decreased more in CRVP group compared to LBBP (both P<0.05) (Figure 2). Conclusion LBBP causes less sequential changes in LV deformation patterns, septal flash and apical rocking, compared to CRVP and LRVP. With this, LBBP appears to preserve LV function better than RVP. CRVP and LRVP did not differ in electro-mechanical changes or LV remodeling. Funding Acknowledgement Type of funding sources: Public grant(s) – National budget only. Main funding source(s): Research Foundation Flanders (FWO) project grant

Introduction Leadless right ventricular (RV) pacing has been recently proposed as alternative to conventional pacemakers (PM's). While RV pacing with a conventional PM is known to cause deterioration of left ventricular (LV) and RV systolic function over time, the effects of leadless PM's are currently under-explored. In this prospective and randomized study, we hypothesized that the effect of leadless RV pacing over time on both LV and RV systolic function is not inferior to conventional RV pacing. Methods Fifty-one age-matched patients with a guideline indication for a PM were prospectively recruited and randomized to undergo implantation of either (i) a leadless PM, or (ii) a conventional PM. Patients underwent echocardiography prior to (BL), and at 6 and 12 months (M6 & M12) after PM implantation. All imaging after implantation was performed during active pacing. Analysis included LV ejection fraction (LVEF), LV global longitudinal strain (GLS), and RV free wall (FW) strain. Results Twenty-seven patients were implanted with a leadless PM, while twenty-four received a conventional PM. Median age was 82 (80–87) years. At BL, average LVEF and LV GLS were normal and similar in both groups. At M12, both LVEF (−12%) and LV GLS strain (−5%) decreased significantly in both study groups (ANOVA p<0.0001, see Figure 1). RV FW strain decreased only significantly in patients with conventional PM (−4%; ANOVA p=0.031, see Figure 1; post-hoc test BL vs. M12: p=0.029). None of the tested variables, at none of the time points, showed significant difference between the leadless and conventional PM study groups (all p>0.05). Median pacing percentage was 68.2% and similar in both study groups (at all time-points p>0.05). Conclusions Both patients with leadless and conventional PM's demonstrate a decrease in LV and RV systolic function, 12 months after implantation. While LV function decrease was similar between both groups, RV function decrease was most prominent in patients treated with conventional PM's. Our data suggest that leadless pacing is not inferior to conventional pacing with regard to the effect on cardiac function. Funding Acknowledgement Type of funding sources: Foundation. Main funding source(s): Research Foundation Flanders (FWO) post-doc grant