No abstract

High magnetocrystalline anisotropy CoPt particles with an average size of 8 nm were synthesized by the superhydride reduction of CoCl2 and Pt(acac)2 at a high temperature. As-made particles showed a disordered face-centered cubic lattice and were superparamagnetic. Upon heat treatment at temperatures above 600 °C, the particles transformed to the L10 phase, as indicated by the appearance of the superlattice peaks in the x-ray diffraction and high magnetocrystalline anisotropy. The temperature dependence of the coercivity of nanoparticles annealed at 650 °C was measured from 10 to 300 K and analyzed using a Sharrock formula. After annealing at 650 °C, the anisotropy of the nanoparticles was K∼1.7×107 erg/cm3.

A monodispersed Mo atom supported by a defective borocarbonitride monolayer has been shown to be a durable, efficient and selective N2 reduction electrocatalyst.