An azine linked covalent organic framework, ACOF, has been constructed via hydrazine hydrate and aldehyde group building unit with hydroxyl group in situ under the solvothermal condition. ACOF possesses good...
Two new imine-linked covalent organic frameworks (NI-COF-1 and NI-COF-2) have been designed and conducted through Schiff base condensation reactions. NI-COFs displayed good porosity, stability, and crystallinity via the flexible units/fluorine...
The phenothiazine-based porous organic polymers (PTA-POPs) were constructed through a facile and cost-effective method. We used commercial phenothiazine as aromatic building units, formaldehyde dimethyl acetal (FDA) as a crosslinker under the catalysis of anhydrous FeCl 3 , which afford PTA-POPs with high yield. The phenothiazine-based porous organic polymers pos-sessed good porosity, excellent thermal stability, and rich heteroatom sites in the skeleton. Cationic PTA-POP (C-PTA-POP) was further synthesized via a simple process. Interestingly, the C-PTA-POP exhibited highly effective iodine vapor capture up to 3.69 g g À 1 , which is ranked the excellent performance among the reported POPs.
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