The existing methods cannot achieve rapid mass decomposition and multi-element analysis of graphite ore samples. In this study, it is found that molten lithium metaborate can destroy the structure of graphite, causing graphite C to be oxidized and decomposed in an oxygen environment. We have established a method system for testing graphite ore samples with lithium metaborate at 950°C melting-ultrasonic extraction-ICP-AES multi-element (Al, Ca, Fe, K, Mg, Mn, Na, P, Si, and Ti) testing.The verification results of the national first-level reference materials show that the detection limit of this method is low and the accuracy and precision are good. The results of the measured samples show no significant difference between this method and the classical chemical analysis method. This method has the following advantages over the existing ones: simple operation process, faster decomposition and testing, less reagent usage, less sample contamination, and better results reproducibility.