Changes of groundwater level, ranging from a fall of 11.10 m to a rise of 7.42 m, induced by thrust faulting during the 1999 M w 7.6, Chi-Chi earthquake have been recorded in 276 monitoring wells in Taiwan. Most coseismic falls appeared near the seismogenic fault as well as other active faults, while coseismic rises prevailed away from the fault. Coseismic groundwater level rises and falls correlated fairly well with hypocentral distance in the vicinity of the thrust fault. We found a major difference of coseismic changes in wells of different depths at most multiple-well stations. The recovery process of coseismic groundwater level changes is associated with the confining condition of the aquifer. Cross-formational flow is likely to play an important role in groundwater level changes after the earthquake. In the hanging wall of the thrust fault, an abnormal decline of groundwater level was observed immediately before the earthquake. The underlying mechanism of the unique preseismic change warrants further investigation.
A new cadmium croconate (C5O5(2-)) complex, [Cd2(C5O5)2(4,4'-bpy)(H2O)]infinity (4,4-bpy=4,4'-bipyridine) with an extended network has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction studies. The title compound crystallizes in the monoclinic system, space group P2(1)/n, with empirical formula C20H12Cd2N2O12, a=15.9623(3) A, b=7.5837(1) A, c=18.1181(3) A, beta=99.95(2) degrees, and Z=4. Structural determination reveals that the title compound has a bilayered network, containing two crystallographically independent Cd(II) ions in different coordination environments. Cd(1) lies in a distorted pentagonal bipyramidal environment, consisting of three croconate ions and one 4,4'-bpy nitrogen donor, while Cd(2) lies in a distorted octahedral environment, consisting of two croconate anions, one 4,4'-bpy nitrogen donor, and one water molecule. Of the two crystallographic independent croconate ligands, one presents a bis-bidentate adjacent mu3-coordination mode and the other a new bidentate/three-adjacent mu5-coordination mode. A two-dimensional hybrid layer is formed by two rectangular boxes as the building units through the connectivity between Cd(II) and croconate and 4,4'-bpy ligands.
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