Effective optical parametric oscillation (OPO) at room temperature was demonstrated by a periodically poled 1.0 mol% MgO-doped stoichiometric lithium tantalate (Mg:SLT) crystal. The slope conversion efficiency of total output power was ∼65% and the maximum output power was 655 mW at 1.3 W pumping without photorefraction. The difference of the OPO performance was investigated between 0.5 and 1.0 mol % Mg:SLT crystals, and a 1.0 mol % MgO-doped device exhibited better OPO performance and high resistance of photorefraction. The effective nonlinear coefficient of deff was found to be 10pm∕V by single-pass first-order quasiphase matched second-harmonic generation at 1064 nm.

The fragmentation of peptides and oligosaccharides in the gas phase was investigated by means of electrospray ionization Fourier transform ion cyclotron resonance (FTICR) mass spectrometry coupled with dissociation by a laser-cleavage infrared multiphoton dissociation (IRMPD) technique. In this technique, an IR free-electron laser is used as a tunable source of IR radiation to cause cleavage of the ionized samples introduced into the FTICR cell. The gas-phase IRMPD spectra of protonated peptides (substance P and angiotensin II) and two sodiated oligosaccharides (sialyl Lewis X and lacto-N-fucopentaose III) were obtained over the IR scan range of 5.7-9.5 microm. In the IRMPD spectra for the peptide, fragment ions are observed as y/b-type fragment ions in the range 5.7-7.5 microm, corresponding to cleavage of the backbone of the parent amino acid sequence, whereas the spectra of the oligosaccharides have major peaks in the range 8.4-9.5 microm, corresponding to photoproducts of the B/Y type.

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