A Cu-catalyzed asymmetric 1,6-conjugate addition of in situ generated para-quinone methides (p-QMs) with β-ketoester has been developed to construct the ketoester skeleton bearing adjacent tertiary-quaternary carbon stereocenter in good yields...
An efficient visible light-induced oxidative α-hydroxylation of β-dicarbonyl compounds has been developed using structurally simple ethylenediamine–copper(ii) as a catalyst.
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