Polyhedral metallocalixarene nanocage cluster based on pure Ti(IV) ion are to our knowledge un-known hitherto. Herein we reported the first Ti(IV)-based metallocalixarene nanocage cluster by assembling a [Ti13O14] cage with...

A large polymolybdate-templated {Ag49Mo16} cluster protected by six thiacalix[4]arene (TC4A) molecules was synthesized by a one-pot solvothermal reaction. Structural analysis shows that the {Ag49Mo16} is assembled by inserting a [Mo6O22]8-...

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High-valence Ti(IV)-based metallocalixarene coordination cages that are linked by oriented ancillary ligands are unknown so far. Herein, the first family of tunable calixarene-based coordination cages of Ti(IV) with a framework...