To design a time-dependent control recipe which can ensure the consistently suitable growth condition in an unsteady growth system with dynamic environmental changes, an adaptive control method based on high-speed...
For
the solution growth of silicon carbide, solvent inclusions
are significant technological issues, and methods to suppress the
formation of solvent inclusions are investigated in this study. Experimental
observations show that solvent inclusions are formed behind the cellular
structures. A phase field model is used to reproduce the formation
process of cellular structures and solvent inclusions. Simulation
results indicate that slight perturbations of the step front can convert
into cellular structures in the case of insufficient supply of carbon,
and the overdeveloped cellular structures consequently result in solvent
inclusions. Accordingly, several schemes can be suggested by the simulation
model to suppress the formation of cellular structures by enhancing
the carbon supply. By increasing the carbon diffusion coefficient,
cellular structures can be suppressed. Moreover, the step height and
the solution flow direction also play an important role in suppressing
the cellular structures. This study provides a comprehensive understanding
of the formation process of cellular structures and solvent inclusions.
A growth process with a high diffusion coefficient and opposite solution
flow to the step flow direction was proposed to suppress the formation
of cellular structures. The proposed numerical model could be applied
in other solution crystal growth methods.
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