This work focuses on the linear viscoelastic behaviour at length scales shorter than an entangled strand and attempts to connect it to the nonlinear behaviour (from data in literature) in fast extensional flow where such short length scales play an important role. We have measured the linear viscoelasticity at high frequencies in the transition to glassy regime for a series of polystyrene (PS) melts and solutions. When the samples are compared at the same T ref -T g , where T ref is the reference temperature and T g is the glass transition temperature, their third crossover points (near the glassy regime) of G' G'' plots are located at the same frequency. While the unentangled styrene oligomer behaves as a solvent in the flow and rubber plateau regimes, it contributes the same as the PS melts in the transition regime, unless the chain length is close to a Kuhn segment. In fast extensional flow, using τ 0 as the time scale and G 0 as the modulus scale, where τ 0 and G 0 are both associated with the third crossover point, the normalized steady-state extensional viscosity seems to depend on the number of Kuhn segments per chain, but not on the PS fraction. This is probably due to the contribution from the styrene oligomer solvent. However, fracture may happen before the steady state if the stretched polymer chains are close to their theoretical maximum stretch ratio.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
customersupport@researchsolutions.com
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.