A photo-induced transition-metal-free regioselective hydroborylation of α,β-unsaturated carbonyl compounds is developed. The PhSSPh reagent was employed as the photocatalyst, and NHC-BH3 was used as the boron source. This transformation shows...

Semi-rational design and iterative combinatorial mutation of AmPNP with gratifyingly improved activity toward steric impediment of 2-halogenated-2′-deoxyadenosine biosynthesis.

Herein we disclose a facil route to spirocyclic oxazole derivatives via the [3 + 2] cycloaddition reactions between 2-arylidene cycloalkanones and azaoxyallyl cations which formed in situ from α-halohydroxamates in...

An N–H functionalization of O-substituted hydroxamic acid with diazo esters under blue LED irradiation conditions has been developed.