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Two blue donor-acceptor uorophores with 1,4,5-triphenylimidazole as the electron-transporting unit and phenothiazine as the hole-transporting unit were synthesized by grafting 1,4,5-triphenylimidazole moieties onto 3-and 3,7-position of the phenothiazine core and characterized by spectroscopic methods.Their thermal stability, photophysical, electrochemical and electroluminescence properties were systematically investigated. These compounds exhibit good thermal stability and show blue emission in dichloromethane solution and thin solid lms. The solution-processed doped devices were fabricated by using these uorophores as the emitting dopant in 1,3-bis(N-carbazolyl)benzene host, in which the device fabricated from the uorophore containing two 1,4,5-triphenylimidazole moieties exhibited blue emission with a luminance of 648 cd/m 2 and external quantum e ciency of 1.48%.