A series of novel Pt-modified Cu-Fe-La/g-Al 2 O 3 catalysts were prepared by an incipient-wetness impregnation method, and their performances were evaluated in catalytic wet air oxidation (CWAO) of printing and dyeing wastewater (PDW). The as-prepared catalysts were characterized by X-ray photoelectron spectroscopy (XPS), nitrogen adsorption-desorption, X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), Raman spectroscopy, and temperature programmed reduction by hydrogen (H 2 -TPR). The effects of catalyst composition and calcination temperature on the catalytic performance were investigated. The chemical oxygen demand (COD) removal efficiency and decolorization rate are satisfactory over Cu 1.5 Fe 1.5 La 3 /g-Al 2 O 3 catalyst, with poor stability under CWAO conditions. In contrast, catalytic performance and stability of all Pt-modified catalysts are significantly improved. With increasing calcination temperatures from 350 C to 750 C, the activity of the catalysts significantly decreases from 97.3% to 84.6%, and the size of the particles varies from 4.71-6.95 nm. The XRD, HRTEM, and XPS results indicate that the Pt , and the incorporation of Pt increases the binding energies (BEs) of the metal elements in the catalyst, owing to synergistic interactions between the Pt and the Cu, Fe, and La elements. After five cycles, the COD removal efficiency and decolorization rate for PDW over the Pt 1 Cu 1 Fe 1 La 3 /g-Al 2 O 3 catalyst calcined at 650 C remain comparable with the fresh catalyst, indicating that Pt-modified Cu-Fe-La/g-Al 2 O 3 ternary oxide is a promising catalyst with high activity and stability for CWAO treatment. Fig. 1 Influence of components on the activity and stability of catalysts. (a) COD removal efficiency, (b) decolorization rate, (c) metal leaching, ()) Pt