A novel hole-transporting material with high singlet and triplet excitation energy levels was developed. Quantum efficiency of a fluorescent organic light-emitting diode (OLED) using this material as a hole-transporting layer can be increased because of facilitated triplet-triplet annihilation (TTA) due to exciton confinement in an emission layer. Furthermore, this material has a deep highest occupied molecular orbital level because of the absence of triarylamine structure. This feature also contributes to the increase in the quantum efficiency, owing to inhibition of a low-energy exciplex formed between the material and a host in the emission layer. Achieved consequently was a blue fluorescent OLED exhibiting a high external quantum efficiency of 11.9% and a long half-decay time of 8,000 h at 1,000 cd/m 2 . By the device analysis including time-resolved electroluminescence measurements, it was confirmed that TTA contributes to the high efficiency.
To clarify the origin of the major donor states in indium gallium zinc oxide (IGZO), we report measurement results and an analysis of several physical properties of IGZO thin films. Specifically, the concentration of H atoms and O vacancies (V O ), carrier concentration, and conductivity are investigated by hard X-ray photoelectron spectroscopy, secondary ion mass spectroscopy, thermal desorption spectroscopy, and Hall effect measurements. The results of these experiments suggest that the origin of major donor states is H occupancy of V O sites. Furthermore, we use first-principles calculations to investigate the influence of the coexistence of V O and H in crystalline InGaO 3 (ZnO) m (m ¼ 1). The results indicate that when H is trapped in V O , a stable complex is created that serves as a shallow-level donor. V C 2014 AIP Publishing LLC.
We developed a high‐performance 3.4‐in. flexible active‐matrix organic light‐emitting diode (AMOLED) display with remarkably high resolution using an oxide semiconductor in a backplane, by applying our transfer technology that utilizes metal separation layers. Using this panel, we also fabricated a prototype of a side‐roll display for mobile uses. In these AMOLED displays, a white OLED combined with a color filter was used in order to achieve remarkably high resolution. For the white OLED, a tandem structure in which a phosphorescent emission unit and a fluorescent emission unit are serially connected with an intermediate layer sandwiched between the emission units was employed. Furthermore, revolutionary technologies that enable a reduction in power consumption in both the phosphorescent and fluorescent emission units were introduced to the white tandem OLED.
-We succeeded in developing a single-unit hybrid organic light-emitting diode (OLED) device with efficient light emission from both a phosphorescent layer and a fluorescent layer. The single-unit hybrid OLED achieved a power efficiency higher than that of a two-unit hybrid tandem OLED with phosphorescent and fluorescent layers.
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