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Measuring the expected impact of China’s energy transition on carbon dioxide (CO2) mitigation and identifying the key influencing factors in different economic sectors will help to provide better policy recommendations for CO2 emission reduction. Based on the prediction results of China’s CO2 emissions in 2030 under the baseline scenario and the target scenario, this study constructs the control group and the treatment group of the energy transition policy quasinatural experiment and then uses the difference in difference (DID) model to evaluate the CO2 emission reduction effect of China’s energy transition policy. The results reveal that the energy transition policy has a significant impact on CO2 emission reduction and helps to achieve China’s 2030 carbon emission reduction target. The impact of energy structure transition on CO2 emission reduction has significant sectoral heterogeneity, which has a positive reduction effect in the industry sector, wholesale and retail sectors, and accommodation and catering sectors, but its reduction effect is not obvious in transportation, storage, and postal sectors. It is suggested that China should implement the sector-differentiated CO2 mitigation strategy, focus on improving the industrial sector’s energy efficiency, and promote the clean, low-carbon transition of energy consumption structure in construction, transportation, storage, and postal industries.

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