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The conversion of cellulose to GVL was achieved through a one-pot reaction by integrating the alcoholysis and transfer hydrogen processes under microwave condition.

The development of an efficient solid catalyst for Friedel–Crafts (FC) reactions is of great importance to organic synthetic chemistry. Herein, we reported the hafnium-doped mesoporous silica catalyst Hf/SBA-15 and its first use for Friedel–Crafts alkylation reactions. Catalysts with different Si/Hf ratios were prepared and characterized, among which Hf/SBA-15(20) (Si/Hf = 20:1) was the most active catalyst, offering up to 99.1% benzylated product under mild reaction conditions. The influences of reaction conditions on the product were systematically investigated and compared. Pyridine-IR characterization of the catalyst showed that Lewis acid formed the primary active sites for the Friedel–Crafts alkylation reaction. X-ray photoelectron spectroscopy (XPS) characterization revealed that the electron shift from the Hf center to the silica framework resulted in a more active Lewis metal center for FC reactions. Moreover, the catalyst was successfully applied to the alkylation reaction with different alcohols and aromatic compounds. Finally, the Hf/SBA-15(20) catalyst also showed good recyclability in the recycling runs, demonstrating its high potential of being used for large scale FC reactions in the industry.