New fluoroalkylated oligomeric silane coupling agents containing morpholino groups were prepared by the reactions of fluoroalkanoyl peroxides with trimethoxyvinylsilane and acryloylmorpholine. The modified glass surface treated with these silane coupling agents was shown to have a strong hydrophilicity with good oil repellency, and these fluoroalkylated oligomers are applicable to new flip-flop-type silane coupling agents.

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New fluoroalkylated oligomers containing morpholino groups are prepared by the reactions of fluoroalkanoyl peroxides with acryloyl morpholine; these oligomers show a good solubility in not only water but also common organic solvents, including non-polar solvents, and are applicable to non-ionic fluorinated amphiphilic oligosurfactants owing to reducing the surface tension of both water and in particular rn-xylene quite effectively .