Acylsilanes were found to react with ketones in the presence of a low-valent titanium reagent generated from titanium(IV) chloride and zinc, giving the corresponding reductive acylated compounds.
TiCl 4 -Zn Induced Reductive Acylation of Ketones with Acylsilanes.-Low-valent titanium generated from TiCl 4 and Zn induces a reductive acylation of ketones with acylsilanes. -(SAKURAI, HIDEHIRO; IMAMOTO,
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